The European Union is taking steps to increase sanctions against Russia over what many believe is a planned annexation of Ukraine's Crimea region.

Today's referendum in Crimea on secession has been called illegal by the EU and the US, and EU foreign ministers will decide tomorrow whether to impose asset freeze and visa sanctions and, if so, who to target.

"The referendum is illegal and illegitimate and its outcome will not be recognised," European Council President Herman Van Rompuy and Commission President Jose Manuel Barroso said in a joint statement.

EU diplomats were working feverishly over the weekend to set up a list of Russian and Moscow-leaning officials from Ukraine who have been involved in pushing for the southern peninsula's secession and possible annexation. Diplomats said member states arrived at weekend talks with different suggestions, so a common list could be drawn up for tomorrow's meeting of the 28 foreign ministers to make a final decision.

The joint Van Rompuy-Barroso statement said the foreign ministers will "decide on additional measures" against Russia.

They would likely include military officials who ordered Ukrainian troops to leave their barracks in Crimea and others who were responsible for breakaway actions there. On the other hand, diplomats said they would shy away from economic operators at the moment.

Depending on developments in Moscow and Ukraine, further sanctions could follow during a two-day summit of EU leaders starting on Thursday.

An EU summit last week suspended talks with Russia on a wide-ranging economic pact and a visa agreement.

On top of that, the EU could move quickly, possibly within a week, to sign the political chapters of a far-reaching association agreement with the provisional government in Kiev, underscoring its support for the new Ukraine government.

EU diplomats in several capitals made it clear the West is unwilling to give up Crimea in the hope of preventing Moscow from moving into eastern Ukraine.

If Moscow takes further measures to acerbate the crisis, EU leaders already have threatened what they have called "far-reaching consequences for relations in a broad range of economic areas".

It would set off a tit-for-tat game of sanctions, which the EU hopes would increasingly isolate Russia on the global stage. Moscow says it is convinced economic sanctions would hurt the EU as much as Russia itself.

Russia is the EU's third-largest trading partner, mainly because of oil and gas imports, with the EU being its biggest gas consumer. Germany, for example, gets 35% of its supplies from Russia.

Russia, in turn, buys everything from machinery to cars from Europe, its biggest trading partner, with exports to Russia totalling 123 billion euros in 2012.

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